The only way I can get the durability to go down on this is to hit a mob, even breaking blocks doesn't do the trick.
Code:
lightningwand: Id: 369 Data: 0 Display: '&7Electric Wand' Lore: - '&6Your hand tingles with' - '&6electric power' - '' - '&dRight click to cast' - '' - '&7Durability 5 / 5' Skills: - skill{s=lightningwand;sync=true} @TargetLocation ~onUse